Abstract

When mechanical vibration (56 Hz) of each of seven dipyridinium dications, 1-7 (100 mg each), was conducted with a stainless steel ball (6.0-mm diameter, 890 mg) in a stainless steel-made twin-shell blender (7.8-mm diameter, 24 mm long) for 30 min at room temperature under strictly anaerobic conditions, the powder surfaces of four derivatives, 1-4, turned to a deep blue-purple in color, and nearly isotropic broad single-line ESR spectra were observed in the resulting powders, which can be ascribed to the formation of the corresponding monocation radicals in 1-4 resulting from a solid-state single electron transfer (SSET)

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