Abstract
The oxime complexes 1 have structures analogous to imine complexes. Such oxime complexes have proven suitable as educts for the synthesis of azaalkenylidene complexes 2 of d‐electronrich transition metals. The cleavage of water from 1 with formal hydridic hydrogen and an N‐bonded OH‐group to give 2 proceeds remarkably smoothly [CRR′ = cyclohexylidene or CMe2; {Os} = (C6H6)(PMetBu2)Os]. equation image
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Schedule a callMore From: Angewandte Chemie International Edition in English
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