A novel narrow band blue-emitting phosphor Rb2ZrSi3O9: Eu2+ with low thermal quenching and high quantum efficiency

Abstract

Developing phosphors with narrow band emission and excellent performance is the main goal of current leading research. In this study, a novel narrow band blue-emitting phosphor Rb2ZrSi3O9: Eu2+ was prepared that can be fully excited by near ultraviolet (NUV) light, emits a bright blue light peak at 470 nm, and has a full width at half maximum (FWHM) of 60 nm. The synthesized Rb2ZrSi3O9: Eu2+ had excellent photoluminescence properties that were reflected in its good thermal stability (up to 82%) and high internal quantum efficiency (up to 75%). These remarkable luminescence properties were mainly ascribed to the highly symmetric and dense crystal structure composed of [Si3O9]6- ring pairs. Multiple emission centers in the Rb2ZrSi3O9: Eu2+ phosphor were confirmed through the photoluminescence (PL) spectra and time-resolved (PL) spectra. A bright warm WLED device with a low correlated color temperature (3386 K) and high color-rendering index (CRI~89.3) was produced by combining the blue phosphor with (Sr, Ba)2SiO4: Eu2+ and CaAlSiN3: Eu2+ and NUV (380 nm). The results indicate that Rb2ZrSi3O9: Eu2+ could be a promising phosphor for use in WLEDs.