A novel dual-channel chemosensor for CN− using asymmetric double-azine derivatives in aqueous media and its application in bitter almond

Abstract

In this paper, we have designed and synthesized a novel sensor L1 based on asymmetric double-azine derivatives, which showed both “naked eye” recognition and fluorescence responses for CN− in DMSO/H2O (v/v=4:1, pH=7.20) solution. This simple sensor L1 could distinguish CN− from coexisting anions via the way of deprotonation and sensing mechanism of intramolecular charge transfer (ICT), and the minimum detection limit on fluorescence response of the sensor L1 towards CN− was down to 9.47×10−7M. Moreover, we have successfully utilized the sensor L1 to detect CN− in bitter almond. Test strips containing L1 were also prepared, which could act as a practical colorimetric tool to detect CN− in aqueous media.