Abstract
The light-oxidation degradation processes of Zn(dmid)(phen)2 (dmid=4,5-dimercapto-1, 3-dithiole-2-one, phen=1, 10-phenanthroaline) in pyridine solvent has been monitored. It has been found under the light, dmid2− of Zn(dmid)(phen)2 in pyridine solution could generate NCS− and NCS− replaces dmid2− to form Zn(NCS)2 (phen)2 simultaneously. The crystal structure of Zn(NCS)2(phen)2 has been determined. In the crystal of Zn(NCS)2(phen)2, two NCS− ligands are arranged in syn-configuration, and there is strong ππ interaction between the two adjacent parallel phen.
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