A novel composite (FMC) to serve as a durable 3D-clam-shaped bifunctional cathode catalyst for both primary and rechargeable zinc-air batteries

Abstract

Novel and highly durable air cathode electrocatalyst with three dimensional (3D)-clam-shaped structure, MnO2 nanotubes-supported Fe2O3 (Fe2O3/MnO2) composited by carbon nanotubes (CNTs) ((Fe2O3/MnO2)3/4-(CNTs)1/4) is synthesized using a facile hydrothermal process and a following direct heat-treatment in the air. The morphology and composition of this catalyst are analyzed using scanning electronic microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX). The morphology characteristics reveal that flower-like Fe2O3 particles are highly dispersed on both MnO2 nanotubes and CNT surfaces, coupling all three components firmly. Electrochemical measurements indicate that the synergy of catalyst exhibit superior bi-functional catalytic activity for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as well as stability than Pt/C and IrO2 catalysts. Using these catalysts for air-cathodes, both primary and rechargeable zinc-air batteries (ZABs) are assembled for performance validation. In a primary ZAB, this 3D-clamed catalyst shows a decent open circuit voltage (OCV, ∼1.48V) and a high discharge peak power density (349mWcm−2), corresponding to a coulombic efficiency of 92%. In a rechargeable ZABs with this bifunctional catalyst, high OCV (>1.3V) and small charge-discharge voltage gap (<1.1V) are achieved along with high specific capacity (780mAhg−1 at 30mAcm−2) and robust cycle-life (1,390 cycles at cycle profile of 20mA/10min).