A novel CoMoO4 enwrapped ZIF-8 nanocomposite with enhanced visible light photocatalytic activity

Abstract

A hybrid nano catalyst, CoMoO4 anchored zeolitic imidazolate framework-8 (ZIF-8) has been synthesized by simplest in-situ chemical method. The characterization results showed that the CoMoO4@ZIF-8 composites had a crystalline structure with a uniform distribution of the Cobalt molybdate particles on the ZIF-8 surface. The FTIR spectra revealed the presence of characteristic peaks for both ZIF-8 and CoMoO4, indicating the successful incorporation of the metal molybdate into the ZIF-8 framework. The SEM-EDS analysis showed that the CoMoO4 nanoparticles (NPs) have been evenly distributed on the ZIF-8 surface. In HRTEM, some rod-like CoMoO4 is observed on the surface of the ZIF-8 material, which is stacked in a disorderly manner and a porous channel structure is formed. The photocatalytic activity of the CoMoO4@ZIF-8 has been evaluated using the degradation of methylene blue (MB) and antibiotic Ciprofloxacin (CIP) under visible light. The optimal photocatalytic activity was achieved with the CoMoO4@ZIF-8 composite, which showed a degradation efficiency of 100% under visible light after 40 min of irradiation. In conclusion, the CoMoO4@ZIF-8 composites showed enhanced photocatalytic activity under visible light, and it exhibited the best performance compared with pure CoMoO4 and ZIF-8.