Abstract
Aryl-substituted hexacarbonyl(hexapentaene)diiron complexes undergo facile intramolecular CC bond cleavage on treatment with [Fe3(CO)12] to yield the corresponding bis(µ3,η2-allenylidene)–iron complexes; the X-ray crystal structures of phenyl-substituted bis(µ3,η2-allenylidene)–iron and related allenylidene complexes are determined.
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