A novel application of micro-EDM process for the generation of nickel nanoparticles with different shapes

Abstract

ABSTRACTThis article explains production of nickel nanoparticles through a micro-electrical discharge machining (EDM) process with a combination of different process parameters. The production of nickel nanoparticles was carried out in a dielectric medium (deionized water) with developed micro-EDM while polyvinyl alcohol worked as the stabilizing agent. The characterization of nickel nanoparticle was done by scanning electron microscope (SEM), Energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), UV–Vis spectroscopy, and Fourier transform infrared (FTIR) analysis. From this investigation, the mean crystal size of the nickel nanoparticles was found to be in the range of 15–20 mm for a pulse-on time variation of 2–0.3 µs and the crystal size was found to decrease with the decrease of pulse-on time. It was also observed that with this decrease, the shape and size of nickel nanoparticles change from spherical to needle-like. The dispersion stability of nickel nanofluid was determined by viscosity measurements and the dynamic viscosity was noted to decrease by decreasing the pulse duration. From the FTIR spectrum results, it was confirmed that the synthesized nickel nanoparticles in deionized water were pure and monolithic. UV–Vis–NIR spectroscopy depicted that the band gap energy increases with a reduction in the pulse-on time and obtains a higher band gap (5.31 eV) for 0.3 µs pulse-on time.