A novel activation-hydrochar via hydrothermal carbonization and KOH activation of sewage sludge and coconut shell for biomass wastes: Preparation, characterization and adsorption properties

Abstract

A two-stage method of hydrothermal carbonization and chemical activation technology was applied to prepare a novel, large surface area and rich-pore structure activation-hydrochar from sludge sewage and coconut shell due to its mild, low-cost, and well-developed merits. The pore-making mechanism of activation-hydrochar was discussed by FT-IR, XPS, SEM, TG, TG-MS, XRD, and BET characterization. These results illustrated that the first stage of hydrothermal carbonization achieved the rich-pore structure hydrochar via dehydration, decarboxylation, deamination, and rearrangement reactions. The subsequent KOH activation was conducive to the pore-forming process. Specifically, the pore structure of activation-hydrochar was ameliorated and abundant active adsorption sites were obtained by the modification. The adsorption properties of activation-hydrochar on Methylene Blue (MB) and Congo Red (CR) were systematically investigated, and the max adsorption capacities of those were obtained with 623.37 mg/g and 228.25 mg/g, respectively. The pseudo-second-order kinetics and Langmuir models were both fit to elucidate the adsorption process for both dyes. Thermodynamics revealed adsorption performance accompanied by the spontaneous and endothermic processes. In general, the research clearly indicated the synthesis route for activation-hydrochar, and its further adsorption performance, capacity, and mechanism on MB and CR. This research demonstrated that activation-hydrochar with the abundant surface area and rich-pore structure made it a candidate for the production of effective adsorption material. It is prospective to achieve the utilization of wastes and its further application in wastewater treatment.