Abstract
A novel cadmium metal organic framework, {[Cd(L)(H2O)]∙THF}n (1), has been synthesized solvothermally using a newly synthesized ligand (L=4-(((1 H-imidazol-2-yl)methylene)amino)benzoic acid). Complex 1, is a 3D supramolecular framework having 2D hydrogen bonded undulated sheets. The network contains solvent accessible void volume of 34.0% which is occupied by THF solvent molecules. The compound exhibits a (4,4) connected binodal network. Solid state photo luminescent property of 1 in different solvents has also been investigated which demonstrate distinct solvent dependent luminescent spectra.
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