Abstract
Treatment of 2-methyl-1H-imidazole-4,5-dicarboxylic acid (H3MIA) with Co(NO3)2 in the presence of 4,4′-bipyridine (4,4′-bipy) under hydrothermal condition, yielded one novel two-dimensional (2-D) coordination polymer [Co(HMIA)(H2O)(4,4′-bipy)0.5]·H2On (1). Single-crystal structural study reveals that the complex incorporates alternate left– and right–handed helical chains by 4,4′-bipy linkages. This is the first example of 2-D Co(II) helical coordination polymer with mixed HMIA and 4,4′-bipy ligands. Its thermal properties are also investigated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.