Abstract
[Ni(pyza)2H2O] n has been synthesized by hydrothermal reaction of 2-pyrazinecarboxylic acid (Hpyza) and Ni(CH3COO)2 · 4H2O in the presence of 1,10-phenanthroline and structurally characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. The title complex displays an infinite zigzag chain structure in which each nickel(II) center is coordinated by three nitrogen and three oxygen atoms to generate a NiN3O3 octahedral geometry. The existence of hydrogen bond leads to formation of the interpenetrating stacked structure.
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