Abstract
Herein, based on single organic ligand as bridging linker and metal trimer as structural nodes, one new pillared-layer metal–organic framework (MOF), Zn3(TDC)4·2DMA (TDC = 2,5-Thiophenedicarboxylic acid, DMA = dimethylamine), has been synthesized and structurally characterized. The pillared-layer architecture is formed by Zn3(TDC)2 layer and pillared TDC ligand where TDC ligand acts as a bifunctional linker. Porous structure of MOF was investigated with potential applications in gas molecule adsorption and metal ion fluorescence sensor.
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