Abstract
A new organic-inorganic hybrid compound constructed from [Mn2V22O64]10− units, H6[(C6H4NO2Cu(H2O)4)]2[Mn2V22O64]·28H2O 1, has been synthesized and characterized by single-crystal X-ray diffraction, IR, powder X-ray diffraction (XPRD) and TG. Compound 1 is composed of dimeric [Mn2V22O64]10− polyoxoanions, metal-organo fragments [(C6H4NO2Cu(H2O)4)]2+ and lattice water molecules. Moreover, a three-dimensional supramolecular structure is formed in 1 by the extensive hydrogen bond interaction among the terminal oxygen atoms of [Mn2V22O64]10− anions, the coordinated waters of Cu2+ ions and crystal water molecules. Compound 1 exhibits remarkable catalytic activity for the heterogeneous oxidation of sulfides under mild condition.
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