Abstract

The new method to determine F - is based on the alteration of the glass surface which possesses no wettability when it is dipped into chromic acid cleaning mixture containing HF. The drop of chromic mixture which forms on the glass surface has a convexity depending upon F - concentration. Measures of the contact angle not directly of this drop but of an bubble (captive bubble) which appears at a bottom of a glass tube. into the test solution, are carried out. Approprriate devices allow even the microdetermination of fluorine. Boric acid and silicic acid are the only reagents able to affect the accuracy of this method.

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