A new EPR dosimeter based on glutamic acid for radiation processing application.

Abstract

L-Glutamic acid (L-GA) pellets (3.8mm × 4mm) and powder dosimeters were studied in the dose range of 0.1-150kGy using the electron paramagnetic resonance (EPR) technique. The EPR spectra of irradiated L-GA pellets showed an EPR signal with eight lines, and the intensity of the signal increased with an increase of absorbed dose. The results obtained in terms of the energy-absorption coefficients suggest a similar performance of the L-GA pellets as compared to alanine pellets. The value of the temperature coefficient for the L-GA pellets during irradiation was around - 0.08%/°C which is lower than that reported for alanine dosimeter, 0.14%/°C. The influence of humidity on the pellet response was found to be negligible; i.e., the increase in response was only about 2% for a relative humidity of up to 94%. The response of L-GA powder reached stability 4h after irradiation and continued to be stable until 47days after irradiation. In contrast, the response of the L-GA pellet dosimeter reached stability 22h after irradiation and continued to be stable until 8days after irradiation. For routine applications, the L-GA pellet dosimeter should be analyzed during the stable period after irradiation, to minimize the uncertainties in dose assessment. The overall two-sigma uncertainties in absorbed dose estimation were 5.1% and 3.9% for the dose ranges of 0.1-15kGy and 15-150kGy, respectively. It is concluded that L-GA pellets represent a promising dosimeter material for quantification of radiation doses in food irradiation, medical sterilization and polymer modification.