Abstract
Reaction of [1,4-C6H4(CH2PPy3)2]Cl2, a cationic ligand, with CuI (MeCN, r.t.) produces ionic [C6H4(CH2PPy3)2][C6H4(CH2PPy3Cu3I5)2] complex, containing structurally unpreceded [Cu3I5]2– inorganic module in the anionic part. The title complex in the solid manifests a weak deep-red luminescence with λmax = 680 nm and lifetimes of 14 and 17 μs at 300 and 77 K, respectively.
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