Abstract
The present paper is devoted to a new approach of the rotational hamiltonian of a non degenerate vibronic state of the semi-rigid molecules. It is based upon two points. Firstly the hermitian operators on a finiten dimensional vector space belong to an2 dimensional euclidian vector space. Secondly, the vector space of the rotational states is a direct sum of irreducible representations of the rotation group. Accordingly in each one of those representations the rotational hamiltonian can be represented by its set of real components on a orthonormal basis of hermitian operators. The components of the reduced hamiltonian of Watson limited to its quartic terms are determined.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Zeitschrift f�r Physik D Atoms, Molecules and Clusters
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.