Abstract
AbstractA new method for the estimation of kinetic parameters in emulsion polymerization systems is presented. This method is based on studies of the evolution of monomer conversion in chemically initiated seeded emulsion polymerization systems. In this paper, homopolymerization under zero—one conditions is considered. The method is based on a fundamental model that includes the free radical balance in the aqueous phase and fundamental parameters such as the entry and exit rate coefficients, the termination rate constant in the aqueous phase, and the rate coefficient for initiator decomposition. These parameters, as well as the propagation rate constant, are the estimable parameters. This method, which uses all available data simultaneously in order to estimate the parameters, is checked by using simulated experimental data generated with exact values of the parameters. The criteria for deciding the usefulness of the present approach are the closeness of the fit to the original data and the match of the estimated kinetic parameters to the exact values of the parameters. It was found that accurate values of the parameters are obtained with the present approach provided that a sufficient number of experiments with a minimum range of variation are available. A study of both the minimum number of experiments and the minimum range of variation of the experimental conditions needed to estimate reliable parameters is presented. Also, the effect of both random and systematic errors is included in this study. Finally, a comparison between the present approach and those previously published in the literature is presented.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.