Abstract
A new 2D MOF with unique [Co5(μ3-OH)2]8+ subunit, [Co5(μ3-OH)2(bcpt)4(bib)2] (1) (H2bcpt = 3,5-bis(3′-carboxyphenyl)-1,2,4-triazole, bib = 1,4-bis(1-imidazoly)benzene) is prepared, which not only shows weak antiferromagnetic interaction between the adjacent Co(II) ion, but also exhibits efficient electrocatalytic hydrogen evolution reaction by the integration with graphene (Gr).
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