A new β-diketonate Dy(III) single‒ion magnet featuring multiple magnetic relaxation processes

Abstract

A β-diketonate mononuclear dysprosium compound, [Dy(TFNB)3(bpy)] (1) (TFNB = 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione, bpy = 2,2′-bipyridine), has been prepared and structurally and magnetically characterized. X-ray crystallographic analysis reveals that 1 contains two crystallographically equivalent Dy(III) ions of which the eight-coordinate geometries uniformly behave as distorted square antiprismatic configurations (D4d). Magnetic investigations demonstrate that 1 displays dual relaxation processes of SMMs behavior with the effective barrier (ΔE/kB) of 23.44 K under 1200 Oe DC field, corresponding to the coexistence of two metal centers in the structure of the compound. The comparative studies of some Dy(III)-based SIMs with TFNB ligand have been conducted as well. Ab initio studies demonstrate that the Kramers doublet ground state is predominantly axial with the gz tensors of two Dy(III) fragments matching the Ising-limit factor (20) anticipated for the pure MJ = ±15/2 state.