Abstract
Abstract The synthesis of BEDT-TTF, bis(ethylenedithio)-tetrathiafulvalene, charge transfer salts with isostructural magnetic and non-magnetic anions M(C2O4)3 3-, where M−1 is Cr, Co or Al is reported. (BEDT-TTF)4[Cr(C2O4)3]. C6H5CN is a semiconductor ([sgrave]TRT = 1–10 Scm−1, EA= 0.09 eV). The EPR spectrum is characterised by one single resonance with a g-value average between those of BEDT-TTF radical and Cr3+. The linewidth is exchange narrowed. The temperature dependence of the susceptibility indicates antiferromagnetic interactions. Infrared data give an optical gap (∼0.2eV) which is consistent with that obtained by the electrical measurement.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
