Abstract

A phenomenological model has been developed to simulate the feature profile evolution of polycrystalline silicon (poly-Si) gate etching in Cl2/O2 plasmas. The model takes into account the deposition of etch products, surface oxidation, and the forward reflection of energetic ions on feature sidewalls. To describe the formation of multilayer SiClx or SiClxOy on feature surfaces during etching, the substrates consist of a number of small cells or lattices of atomic size in the computational domain; this model provides a nanometer-scale representation of the feature geometry and the chemical constituents therein. The inelastic or nonspecular reflection of incoming ions from feature surfaces and the penetration of ions into substrates are incorporated into the model by calculating the trajectory of ions through successive binary collisions with substrate atoms. Etching experiments were performed to evaluate and improve the accuracy of the model. To analyze the effects of the control variables of a plasma reactor on profile evolution, the simulated profiles for different gas flow ratios and incident ion energies were compared with the etched profiles obtained in the experiments. The numerical results reproduced the behaviors of profile anomalies such as sidewall tapering and microtrenches at the corner of the feature bottom, upon varying the incident fluxes of O neutrals and etch by-products, and the incident energy of ions. Moreover, the simulated profiles exhibited passivation layers deposited on feature sidewalls, which is a similar geometry to those obtained in the experiments.

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