Abstract
Silicon (Si) has been considered as the most promising anode material for next-generation high-capacity Li-ion batteries due to its very high theoretical specific capacity. However, the large deformation associated with (de)lithiation and its detrimental consequences like pulverization, loss of electrical contact, and subsequent capacity loss, have long been a roadblock in deploying high-capacity electrodes. Grafting small amounts of Si with graphite has been proven to utilize the higher capacity of silicon and the stability of graphite. The intricacies of interactions between the two active materials and their effect on the overall performance of the composite electrode are still not well known. Here, we present a novel fully coupled multiphysics electrochemical-mechanical model based on 3D microstructure extracted from X-ray tomography scans of Si-C composite electrode. The theoretical framework integrates the large deformation and viscoplastic response of Si, and the two-way coupling between diffusion and interfacial reactions with mechanical stress. The resolution of the pore phase from the silicon and graphite phases allows for the simulation of the Li+ ion kinetics in the composite electrode and influence of the microstructure. The model is employed to study the phenomena of preferential lithiation, crosstalk between active materials, partial utilization due to mechanical influences, and develop strategies to maximize the specific capacity. Lastly, we also explore the potential and avoidance of mechanical damage within active materials and interfacial delamination. The first-of-its-kind 3D microstructure resolved, multi-material model presents a novel tool to simulate the performance of Si-C composite electrode and decode the depth of interactions between the active materials.
Published Version
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