A micromechanical analysis of swelling-induced embrittlement in neutron-irradiated austenitic stainless steels

Abstract

Swelling is commonly observed in austenitic stainless steels irradiated at high doses and high temperatures, such as fuel claddings in Fast-Breeder Reactors (FBR), as a consequence of the formation of irradiation-induced nanovoids. Macroscopic embrittlement has been reported above a critical swelling level. Several physical explanations have been proposed such as void-related fracture mechanisms and phase transformation associated with local changes of microchemistry. In addition, structural effects can affect the critical swelling level, tentatively explained by local corrosion, swelling gradient and bending effects. In order to address these phenomena, an extended experimental database is first presented, based on fuel pins irradiated in the Phénix fast reactor, showing the evolution of conventional tensile properties with swelling. In the present database, 15-15Ti specimens were irradiated from 30 to 120 dpa, with irradiation temperatures ranging from 400 °C to 625 °C and a maximum swelling of 11%. Other data published in scientific literature were also included in the analysis to extend the swelling range up to 30%. SEM and TEM analysis are also summarized to highlight specific embrittlement mechanisms related to the presence of voids. Theoretical analysis and finite element simulations are then performed based on porous materials constitutive equations in order to rationalize the experimental observations. Analytical and numerical results show that swelling-induced embrittlement can be understood from a mechanical perspective as a transition from void growth to void coalescence deformation mode. The effect of the spatial heterogeneity of void distribution is quantified and shown to be a key parameter. Structural effects coming from tests performed on ring and axial tensile specimens and from the presence of a swelling gradient in cladding thickness are also quantified. Numerical results are compared to experimental data, and a good agreement is observed.