Abstract
Interaction of HgI2 with a new long rigid nitronyl nitroxide radical ligand, 2-[4-(2-pyridin-4-yl-vinyl)phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (L), leads to the formation of the mercury-radical complex [Hg2I4L2] n (1). The single crystal structure analysis reveals that 1 exhibits a one-dimensional (1D) ladder structure. Magnetic susceptibility data of 1 were simulated by a uniform chain model composed of the NIT–NIT dimers, indicating that there exist an antiferromagnetic exchange between the nitroxides within the dimer (J 1 = −8.41 cm−1) and a very weak interdimer antiferromagnetic interaction (J c = −0.39 cm−1).
Full Text
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call