A holistic approach to the assessment of heavy metal levels and associated risks in the coastal sediment of Giresun, southeast Black Sea

Abstract

A seasonal study was conducted to assess the levels, sources, and potential ecological risks of heavy metals (HM) in coastal sediments along the Giresun Coast, located on the southeast coast of the Black Sea. The mean concentrations of HMs as mg/kg were ranked as Fe (27646.37) > Al (27348.55) > Mn (571.87) > Zn (94.16) > Cr (60.64) > Cu (45.66) > Pb (41.37) > Ni (27.29) > Co (14.47) > As (7.36) > Cd (0.20), respectively. At all stations through the year, Al, Cr, Mn, Fe, Co, and Ni were in “the minimum enrichment” class as evaluated by the enrichment factor (EF). As assessed by the contamination factor (CF), all HM levels except Pb, Fe and Cu were “low” or “moderately polluted” at all stations and seasons. With the exception of Cd levels, all HMs in all seasons and stations pointed out “low ecological risk” according to the ecological risk index (Eri). According to the sediment quality guidelines, Ni, Cu and Pb were observed to pose a high ecological risk to habitat. The combined risk assessment indices pointed out low to moderate ecological risk. The study concluded that the region is subject to minimum anthropogenic disturbances in the aquatic environment.