Abstract
Abstract A self-assembly reaction of Cd(NO3)2 · 4H2O, 3-ferrocenyl-5-(2-pyridyl)-pyrazole (Hfcpp), [Ag(SePh)] n , and Et3N in a mixed acetone-water solvent resulted in the formation of a heterometallic complex [Cd2{Ag(SePh)}2 (μ 3-OH2)2(μ 2,η 3-fcpp)4] · 2C3H6O (1) with a phenylselenolate ligand. The two cadmium and two silver centers are linked by four [μ 2,η 3-fcpp]− ligands and two μ 3-OH2 water molecules. Each Cd atom is in a slightly distorted octahedral coordination environment, while each Ag atom shows a distorted tetrahedral coordination geometry, which is composed of two pyrazolyl nitrogen atoms, one selenium atom, and one oxygen atom.
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