Abstract
Two new structurally characterized coordination polymers containing the P 4(NR) 6 ligand system are described. A convenient one-pot synthesis of P 4(NR) 6 (R = benzyl) via reaction of lithiated primary amine with phosphorus trichloride demonstrates an expanded scope for the preparation of this adamantane-type structure. Reactions of P 4(NR) 6 (R = Et, Bn) with cuprous iodide yield different products due to the differences in steric demands of the ligands.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
