Abstract

Investigation of Atomic and molecular (e, 2e) spectra will be discussed in terms of a Green's function approach. The energy, intensity and momentum distribution of energy levels observed by electron coincidence ionization spectroscopy, are directly related to the poles, pole strengths and generalized overlap amplitude of the one particle propagator or Green's function. The theoretical calculation of these observable quantities via the Green's function technique will be discussed. In particular, the position and intensity of satellite (or “shakeup”) lines, relative to the main lines, will be analysed in some detail.

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