Abstract
A glassy carbon electrode (GCE) was consecutively modified with amino groups and phosphate groups, and then loaded with Zr(IV) ions. Fourier transform infrared spectrophotometry, field-emission scanning electron microscopy, energy dispersive X-ray spectroscopy and cyclic voltammetry were used to characterize the morphologies and electrochemical properties. The sensor was used to detect p-nitrophenyl-substituted organophosphorus pesticides, with methyl-parathion (MP) as the model analyte. Under optimized conditions, the oxidation current of square wave voltammetry (typically measured at around -0.28V vs. saturated calomel electrode) increases linearly in the 1.0 to 100ngmL-1 MP concentration range, and the detection limit is 0.25ngmL-1 (at asignal to noise ratio of 3). Average recoveries from (spiked) real water samples are 99.9-102.2%, with relative standard deviations of 0.3-2.6% (n = 3) at three levels. The reliability and accuracy of the method was validated by HPLC. Graphical abstract Zr(IV) modified GCE is prepared via three steps. The electrode shows high specificity and selectivity towards methyl-parathion. And the linear range is 1.0 - 100.0 ng mL-1 with the detection limit as low as 0.25 ng mL-1 with SWV.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
