A fluorescent sensor based on Zn(II)-coodination polymers bearing mixed ligands for the sensitive detection of riboflavine, imidacloprid and nitenpyram

Abstract

Two new 2D Zn(II) coordination polymers (BAO28 and BAO29), formulated as [Zn(DIN)(HPT)]DMF·2H2O (BAO28) and [Zn(DIN)(HPT)]·2H2O (BAO29) (H2HPT = 5‑hydroxy-isophthalic acid, DIN = 1,4-di(imidazol-1-yl)naphthalene and DMF = N,N-dimethylformamide), were successfully synthesized under solvothermal conditions. Fluorescence analysis showed that BAO28 proceeded with a DIN ligand-based emissive fluorescence. More importantly, the recoverable multi-responsive fluorescent sensor BAO28 was used for fluorescent detection of imidacloprid (IMI), nitenpyram (NTP), and riboflavine (VB2) in a neutral buffer solution with high sensitivity and a low detection limit. Moreover, the sensing of the pesticides by BAO28 was mainly due to the competitive absorption of excitation and emission light by the sensor with that of the pesticides. Furthermore, for the sensing of riboflavine, in addition to the internal filtration effect (IFE) and fluorescence resonance energy transfer (FRET) mechanisms, the sensing mechanism was simultaneously attributed to photoinduced electron transfer.