Abstract
DSC measurements in the 25–240°C temperature range have been performed on sulphur—selenium physical mixtures (1.99–95.06 mass% of Se) in order to clarify the interaction mechanism. The experimental results can be interpreted on the basis of an interaction model according to which a S/Se copolymerization process takes place in mixtures with Se contents up to 55 mass%. Beyond the 55 mass% Se content the interaction mechanism appears to shift towards an “anomalous melting” behaviour of the two components.
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