Abstract

AbstractThe results of a differential anomalous X‐ray scattering (DAS) study on lead(II)acetate trihydrate, dissolved in 2‐methoxyethanol, are reported. Anomalous X‐ray scattering at two energies below the L3‐edge of lead (Pb) was used to determine the local environment of Pb and to get more precise information on the complex molecular structure of the liquid. The differential scattering intensities and their Fourier transform, the differential atom pair correlation function (DACPF), were obtained after an intricate data evolution procedure. The analysis of the DACPF provides strong evidence for a dimeric structure of lead(II)acetate trihydrate in the methoxyethanolic solution via lead ‐ oxygen ‐ lead correlation.

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