A cubic perturbed hard-chain equation of state

Abstract

A cubic equation of state is developed on the basis of perturbation theory. The equation is an association of three segments: the hard-sphere, the hard-chain, and the attraction. The expression for each segment was invoked from approximations of computer simulations of rigorous molecular theories of fluids, but compromised to some extent accuracy and theory for simplicity. This model equation is shown to be potentially capable of describing the PVT behavior of real fluids. As limiting cases, the new equation is reduced to expressions for the hard-sphere and the hard-body fluids. It also represents square-well fluids when the hard-chain contribution is eliminated. The square-well equation was found satisfactory in conforming with the molecular simulation results for square-well fluids and their mixtures.