Abstract
A three-dimensional copper-organic coordination polymer based on 3-(4-hydroxypyridinium-1-yl) phthalic acid (H2L) and μ-4,4′-bipyridine (bpy), [Cu(L)(bpy)1/2(H2O)]n (1), has been obtained by hydrothermal synthesis and characterized by elemental analysis, the powder X-ray diffraction (PXRD), UV–vis absorption spectra, and also by single-crystal X-ray diffraction. The crystal is triclinic, space group Pī. The L2– anions of complex 1 as a bridging ligand connect Cu(II) ions to form one-dimensional (Cu2(L)2)n chains, which are linked to build a 2D layer by the bpy ligands. The 3D supramolecular framework of complex 1 are guided or controlled by weak directional interlayer hydrogen bond interactions.
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