Abstract
The thermal decompositions ofβ-AlF3 · 3H2O, AlF3 · 3.5H2O, AlF3 · 1.5H2O,β-AlF3 and hydroxyfluorides of aluminium were investigated. The literature data were complemented with X-ray results. The first stages of decomposition are described. The AlF3 hydrates and hydroxyfluorides were used as model systems in order to interpret the thermal behaviour of α-AlF3 in more detail.
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