A Comparative Study on Color Stability of Anthocyanin Hybrid Pigments Derived from 1D and 2D Clay Minerals

Bin Mu,Aiqin Wang,Shue Li,Xiaowen Wang,Yuru Kang

doi:10.3390/ma12203287

Abstract

Anthocyanin extracted from the fresh blue berry fruits was loaded onto different clay minerals including one-dimensional tubular halloysite and fibrous sepiolite, and two-dimensional lamellar kaolinite and montmorillonite to fabricate reversible allochroic hybrid pigments. The effect of the possible interaction mechanism between anthocyanin and clay minerals on the color stability of hybrid pigments was investigated. Due to the difference in the structures and properties of clay minerals, natural anthocyanin was inclined to be absorbed on the surface and intercalated into the interlayer of 2:1 type layered montmorillonite, while it was mainly anchored on the surface of 1:1 type kaolinite and halloysite. By contrast, it was simultaneously loaded on the surface and confined into the nanochannels and/or grooves of 2:1 type chain-layered sepiolite. Interestingly, the resulting hybrid pigments presented good thermal stability and resistance to chemical reagents, as well as reversible gas-sensitive allochroic behavior in HCl or NH3 gases, especially anthocyanin/sepiolite hybrid pigments due to the shielding effect of the well-defined nanochannels and grooves of sepiolite. Based on this color-change behavior, a simple pH test paper was also prepared with obvious color change at different pH values by coating the filter paper with anthocyanin/sepiolite hybrid pigments.

Highlights

Anthocyanin (ACN) mainly derives from blueberries, grape skins, purple sweet potatoes, acerola juice, and red cabbage [1,2,3,4,5,6,7,8]
The stimulation of the external environments leads to the diversity of ACN color ranging from blue to red, which mainly attributes to the number of hydroxyl groups and methyl groups in the molecular structure of ACN [10,11,12]
The chemical compositions of clay minerals were collected from E3X-ray fluorescence

Summary

Introduction

Anthocyanin (ACN) mainly derives from blueberries, grape skins, purple sweet potatoes, acerola juice, and red cabbage [1,2,3,4,5,6,7,8]. ACN accumulates in the foliage of various plants, such as liverwort and Prunuscerasifera [9]. This water-soluble pigment can impart a variety of vivid colors to above fruits, vegetables, and plants as natural colorants. The stimulation of the external environments (e.g., pH and temperature) leads to the diversity of ACN color ranging from blue to red, which mainly attributes to the number of hydroxyl groups and methyl groups in the molecular structure of ACN [10,11,12]. The more hydroxyl groups, the bluer the colors, while a number of methoxyl groups are associated with red [13]. The color of ACN is unstable and fleeting without any protection due to its Materials 2019, 12, 3287; doi:10.3390/ma12203287 www.mdpi.com/journal/materials

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