A comparative study of temperature broadening of spectral holes burnt in absorption bands of monomers and J-aggregates of a thiacarbocyanine dye

Abstract

J-aggregates and monomers of a thiacarbocyanine derivative are investigated in glassy matrices by spectral hole burning. The temperature dependence (at T = 4.6−20 K) of the width of the hole burnt in the absorption band of aggregates differs qualitatively from that of the hole in the absorption band of monomers. The hole width for J-aggregates does not depend on temperature below 9 K and is equal to 3.3 cm −1. This residual hole width is suggested to be determined by exciton-phonon scattering with phonon emission.