Abstract

Abstract A comparative ferroelectric and NMR studies of the systems Li1+5X M1−XO3 and Li1+XM1−XM′ XO3 (M=Nb, M′=Ti M = Ta; M′=Ti, Zr, Sn) have indicated that plot of TC versus composition can be qualitatively explained on the basis of cationic distribution. The strong drop of TC has been found in systems with all cations in octahedral sites, whereas little change of TC was observed along the solid solutions with Li-ions in interstitial tetrahedral sites.

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