A Comparative Investigation on Adsorption Performances of Activated Carbon Prepared from Coconut Husk Fiber and Commercial Activated Carbon for Acid Red 27 Dye

Abstract

The adsorption of acid red 27 dye on activated carbon fiber and granular activated carbon were studied in a batch system. The effects of initial concentration, agitation time, solution pH and temperature were examined. Adsorption isotherms were described using both the Langmuir and Freundlich models at three different temperatures. It was found that, the Langmuir model fits well with the experimental data a t eac h temper ature. The pseudo-f irst-order, pseudo-second-order and intra-particle dif fusion models were used to e xamine the kinetics data. The r esults obtained showed tha t the empirical kinetics data of activated carbon fiber at 60 and 100 mg/L were w ell described only by the pseudo-second-order model. The intraparticle diffusion was involved at 200 mg/L for activated carbon fiber and at each tested concentration for granular activated carbon. It was observed that activated carbon fiber has a higher adsorption capacity and adsorption rate than that of granular activated carbon. Adsorption thermodynamic parameters were estimated and the values of ΔHo, ΔSo and ΔGo obtained indicate that the adsorption of acid red 27 on activated carbon fiber and granular activated carbon were exothermic and spontaneous processes.