Abstract

The title compound, C12H8N2·2B(OH)3, is best described as a host–guest complex in which the B(OH)3 mol­ecules form a hydrogen-bonded cyclic network of layers parallel to the ab plane into which the 1,10-phenanthroline mol­ecules are bound. An extensive network of hydrogen bonds are responsible for the crystal stability. No π-stacking inter­actions occur between the 1,10-phenanthroline mol­ecules.

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