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https://doi.org/10.1016/j.tetasy.2011.06.033
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Cite Journal: Tetrahedron: Asymmetry |  Publication Date: Jun 1, 2011 |
 Citations: 18 |
Affiliation: Tokyo University of Pharmacy and Life Sciences
The kinetic resolution of 1,1-diethoxyethyl(hydroxymethyl)phosphinate possessing chirality at the phosphorus atom was achieved via a lipase-catalyzed acylation. The product was transformed into the corresponding imine, which in turn is a useful starting material for the preparation of phosphinyl dipeptide isosteres.
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