Abstract
A new mechanically stable and chemically inert resin for solid phase organic synthesis is described. The resin, POEPS-3 ( 1), is prepared by bulk and inverse suspension radical polymerisation of macromonomers consisting of polyethylene glycol 1500 partially derivatised with 3-(4-vinylphenyl)propyl groups. Synthesis of the macromonomer ( 4) is described as well as the properties of the resin which show compatibility with Lewis acids and solvents ranging from toluene to water in polarity.
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