Abstract
Dish it up: The first bowl-shaped o-semiquinone radical with a sodium cation (see picture) has been synthesized, and its 3D spin- and charge-delocalized nature and redox properties have been evaluated. The concave–convex dynamic behavior of the ion pair was also investigated in a quantitative manner using ESR and ENDOR/TRIPLE measurements and sophisticated DFT calculations. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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