Abstract

A novel bimetallic 4d-4f complex, {[HoIII(DMF)6] [MoV(CN)8]·3H2O}n (1) (DMF = N,N’-dimethylformamide), has been synthesized and structurally characterized. The crystalline analyses shown that the complex 1 consists of a one-dimensional (1D) infinite chain, which adopts a 1D zigzag motif, and this is the first structurally characterized example of a 1D structure based on the [Mo(CN)8]3− and Ho3+ building blocks. The complex 1 crystallizes in a monoclinic system of space group P21/c, with a = 10.8672(7), b = 20.920(2), c = 17.9097(7) Å, β = 92.646(4)°, and Z = 4.

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