Abstract

Abstract Three dinuclear palladium(II) complexes with 2,2′-bipyridine (bpy) were synthesized from [Pd(bpy)Cl2] and 3-aminopropanethiol (Hapt) by changing reaction conditions. It was found that Hapt can adopt three different coordination modes (Hapt-κ2S, apt-κN,κ2S, H−1apt-κ2N,κ2S) dependent on its protonation states in this coordination system.

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