Abstract
Abstract The crystal structure of diamagnetic borate chloride Sn2B5O9Cl exhibits two crystallographically independent tin sites which both show pronounced lone-pair activity of the tin atoms. This is reflected in substantial quadrupole splitting in the 119Sn Mössbauer spectrum. The isomer shifts of 3.887(8) and 4.137(7) mm s−1 clearly indicate divalent tin. In agreement with bond valence calculations, the Sn1 atoms have a lower charge and the higher isomer shift, compatible with a higher electron density at the tin nuclei.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
