Abstract
This chapter presents the background and contemporary research accomplishments dealing with smart architectural devices, photovoltaics. The evolution of photovoltaic devices, developments with open challenges, and future opportunities are analyzed and elaborated along with their response characteristic models and variations in graphical analysis. The chapter details the contribution of organic-inorganic solar cell devices and ferroelectric photovoltaics as well as their structural architecture for applications in switchable photovoltaics. Conclusions on device-construction variations, behavioral features with respect to a narrowed bandgap, control over polarization, leakage of current, and intrinsic conductivity are drawn. In continuation, the future scope and challenges are recognized.
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